Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.13091/4352
Title: The role of physicochemical marble processing wastewater treatment sludge in the production of new generation pyrolysis char from waste polypropylene
Authors: Kalem, Merve Sogancioglu
Kurt, Afra Özgan
Göktepeli, Gamze
Önen, Vildan
Ahmetli, Gülnare
Yel, Esra
Keywords: Char
industrial symbiosis
marble processing wastewater sludge
pyrolysis
waste PP
Catalytic Co-Pyrolysis
Thermal-Decomposition
Plastic Wastes
Polyethylene
Degradation
Gasification
Kinetics
Fuel
Cao
Publisher: Taylor & Francis Ltd
Abstract: The effects of marble processing wastewater physicochemical treatment sludge (K1) on polypropylene (PP) waste pyrolysis were investigated by lab-scale batch pyrolysis system. PP-K1 proportions and pyrolysis temperature were studied as variables and both were found to have influences onto pyrolysis char, oil/tar, gas fractions distribution, as well as pyrolysis char characteristics (determined via SEM, EDX, FTIR, TGA and XRD analyses). The influence of K1 could be related to its high mineral composition (CaCO3, CaMg(CO3)(2) and (Mg0.03Ca0.97)(CO3)) which also detected in the char products. K1 acts as catalyst and remained unchanged in thermochemical reactions below 700 & DEG;C. The main thermal degradation of PP occurs around 400-470 & DEG;C, although it starts at about 300-350 & DEG;C, whereas, K1 resulted in more thermal degradation at 300 & DEG;C pyrolysis. As K1 dose increased, pyrolysis chars became more thermally stable with the pyrolysis temperature. Diverse types of chars in terms of porosity, thermal strength and chemical structure were produced with PP + K1 as compared to the PP chars. For example, with 10%-20% K1 doses, the chars are in aromatic structure while chars become aliphatic when K1 dosage increased to 30% or above. The structural diversity made these chars new products that can be used as raw material for subsequent purposes. This study provided a basis for the chars' physical and chemical properties which are needed for further research to develop new generation evaluation areas for them. Therefore, a new symbiotic upcycling approach has been presented for PP wastes and marble processing wastewater treatment sludge.
Description: Article; Early Access
URI: https://doi.org/10.1080/09593330.2023.2224927
https://hdl.handle.net/20.500.13091/4352
ISSN: 0959-3330
1479-487X
Appears in Collections:PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collections
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections

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