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https://hdl.handle.net/20.500.13091/305
Title: | A novel experimental and density functional theory study on palladium and nitrogen doped few layer graphene surface towards glucose adsorption and electrooxidation | Authors: | Çağlar, Aykut Düzenli, Derya Önal, Işık Tezsevin, İlker Şahin, Özlem Kıvrak, Hilal |
Keywords: | Pd Graphene Glucose Electrooxidation Density Functional Theory Formic-Acid Electrooxidation Solar-Energy Conversion Fuel-Cells Carbon Nanotubes Alloy Catalysts Alkaline-Medium Deposition Efficient Anode Pd |
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | Abstract: | At present, few layer graphene (G) and nitrogen doped few layer graphene (N doped-G) are firstly coated on Cu foil via chemical vapor deposition (CVD) method and G and N doped-G coated Cu foil is transferred to the indium tin oxide (ITO) substrate surface to obtain electrodes. Pd metal is electrodeposited onto the N doped-G/ITO electrode (Pd-N doped-G/ITO). Pd-N doped-G/ITO electrode are characterized with advanced surface characterization methods such as Raman spectroscopy and SEM-EDX. Characterization results reveal that G and N structures are succesfully obtained and the presence of Pd on Pd-N doped-G/ITO is confirmed with SEM-EDX mapping. The cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) are employed to examine glucose electrooxidation of G/ITO, N-doped G/ITO, and Pd-N-doped G/ITO electrodes. P-N-dopedG/ITO electrode exhibits the best glucose electrooxidation activity with 2 mA/cm(2) specific activity. Density functional theory (DFT) calculations are also carried out to better understand the interaction of the molecules on Pd modified G (Pd-G) and Pd modified N-doped G (Pd-3NG) surfaces. | URI: | https://doi.org/10.1016/j.jpcs.2020.109684 https://hdl.handle.net/20.500.13091/305 |
ISSN: | 0022-3697 1879-2553 |
Appears in Collections: | Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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