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https://hdl.handle.net/20.500.13091/305
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Çağlar, Aykut | - |
dc.contributor.author | Düzenli, Derya | - |
dc.contributor.author | Önal, Işık | - |
dc.contributor.author | Tezsevin, İlker | - |
dc.contributor.author | Şahin, Özlem | - |
dc.contributor.author | Kıvrak, Hilal | - |
dc.date.accessioned | 2021-12-13T10:23:59Z | - |
dc.date.available | 2021-12-13T10:23:59Z | - |
dc.date.issued | 2021 | - |
dc.identifier.issn | 0022-3697 | - |
dc.identifier.issn | 1879-2553 | - |
dc.identifier.uri | https://doi.org/10.1016/j.jpcs.2020.109684 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.13091/305 | - |
dc.description.abstract | At present, few layer graphene (G) and nitrogen doped few layer graphene (N doped-G) are firstly coated on Cu foil via chemical vapor deposition (CVD) method and G and N doped-G coated Cu foil is transferred to the indium tin oxide (ITO) substrate surface to obtain electrodes. Pd metal is electrodeposited onto the N doped-G/ITO electrode (Pd-N doped-G/ITO). Pd-N doped-G/ITO electrode are characterized with advanced surface characterization methods such as Raman spectroscopy and SEM-EDX. Characterization results reveal that G and N structures are succesfully obtained and the presence of Pd on Pd-N doped-G/ITO is confirmed with SEM-EDX mapping. The cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) are employed to examine glucose electrooxidation of G/ITO, N-doped G/ITO, and Pd-N-doped G/ITO electrodes. P-N-dopedG/ITO electrode exhibits the best glucose electrooxidation activity with 2 mA/cm(2) specific activity. Density functional theory (DFT) calculations are also carried out to better understand the interaction of the molecules on Pd modified G (Pd-G) and Pd modified N-doped G (Pd-3NG) surfaces. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey TUBITAK projectTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [116M004] | en_US |
dc.description.sponsorship | Hilal Kivrak would like to thank you for the financial support for The Scientific and Technological Research Council of Turkey TUBITAK project (project no:116M004). The numerical calculations reported in this paper were fully performed at TUBITAK ULAKBIM, High Performance and Grid Computing Center (TRUBA resources). Visit http://www.truba.gov.tr/for more information. | en_US |
dc.language.iso | en | en_US |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | en_US |
dc.relation.ispartof | JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Pd | en_US |
dc.subject | Graphene | en_US |
dc.subject | Glucose Electrooxidation Density Functional Theory | en_US |
dc.subject | Formic-Acid Electrooxidation | en_US |
dc.subject | Solar-Energy Conversion | en_US |
dc.subject | Fuel-Cells | en_US |
dc.subject | Carbon Nanotubes | en_US |
dc.subject | Alloy Catalysts | en_US |
dc.subject | Alkaline-Medium | en_US |
dc.subject | Deposition | en_US |
dc.subject | Efficient | en_US |
dc.subject | Anode | en_US |
dc.subject | Pd | en_US |
dc.title | A novel experimental and density functional theory study on palladium and nitrogen doped few layer graphene surface towards glucose adsorption and electrooxidation | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1016/j.jpcs.2020.109684 | - |
dc.identifier.scopus | 2-s2.0-85097775460 | en_US |
dc.department | Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümü | en_US |
dc.authorid | Tezsevin, Ilker/0000-0001-5648-3943 | - |
dc.authorwosid | Tezsevin, Ilker/N-2453-2018 | - |
dc.identifier.volume | 150 | en_US |
dc.identifier.wos | WOS:000605608400012 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 57201153766 | - |
dc.authorscopusid | 35224859100 | - |
dc.authorscopusid | 6602188204 | - |
dc.authorscopusid | 55796426000 | - |
dc.authorscopusid | 24766836200 | - |
dc.authorscopusid | 25959155500 | - |
dc.identifier.scopusquality | Q1 | - |
item.grantfulltext | embargo_20300101 | - |
item.openairetype | Article | - |
item.fulltext | With Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
crisitem.author.dept | 02.01. Department of Chemical Engineering | - |
Appears in Collections: | Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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1-s2.0-S0022369720312798-main.pdf Until 2030-01-01 | 8.3 MB | Adobe PDF | View/Open Request a copy |
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