Please use this identifier to cite or link to this item:
https://hdl.handle.net/20.500.13091/991
Title: | Coating of hydrophilic poly(hydroxypropyl methacrylate) thin films via pulsed-initiated chemical vapor deposition method | Authors: | Mercan Sevgili, Emine Karaman, Mustafa |
Keywords: | iCVD Pulsed deposition Polymer Thin film |
Publisher: | SPRINGER | Abstract: | This study demonstrates the coating of poly(hydroxypropyl methacrylate) (PHPMA) thin films from the corresponding monomer HPMA using pulsed-initiated chemical vapor deposition (pulsed-iCVD) method. The advantages of pulsing the power delivered to the filament wires during iCVD through successive on-off duty cycles (DC) are outlined by considering the deposition rates, structure, and morphology of as-deposited PHPMA films. FTIR and XPS analysis of the as-deposited films verifies that pulsing the filament power produces thin films of PHPMA, which is structurally very similar to that synthesized using classical continuous power iCVD. However, there is up to 70% increase in deposition rate upon pulsing the filament power in comparison with the continuous power iCVD. AFM analysis of the as-deposited films shows that the film morphology can be controlled by varying the DC during pulsed-iCVD. At a DC of 85.7%, the most hydrophilic film is observed with a measured water contact angle of 31 degrees. | URI: | https://doi.org/10.1007/s11998-021-00486-w https://hdl.handle.net/20.500.13091/991 |
ISSN: | 1547-0091 1935-3804 |
Appears in Collections: | Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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s11998-021-00486-w.pdf Until 2030-01-01 | 1.29 MB | Adobe PDF | View/Open Request a copy |
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