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https://hdl.handle.net/20.500.13091/67
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Akpınar, Merve | - |
dc.contributor.author | Temel, Farabi | - |
dc.contributor.author | Tabakcı, Begüm | - |
dc.contributor.author | Özçelik, Egemen | - |
dc.contributor.author | Tabakcı, Mustafa | - |
dc.date.accessioned | 2021-12-13T10:19:43Z | - |
dc.date.available | 2021-12-13T10:19:43Z | - |
dc.date.issued | 2019 | - |
dc.identifier.issn | 0003-2697 | - |
dc.identifier.issn | 1096-0309 | - |
dc.identifier.uri | https://doi.org/10.1016/j.ab.2019.113373 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.13091/67 | - |
dc.description.abstract | This paper describes the synthesis of new chiral calix [4]arene derivative having (R)-2-phenylglycinol moiety (compound 6), and its chiral recognition studies for ascorbic acid (AA) enantiomers by using Quartz Crystal Microbalance (QCM). Initial experiments indicated that the outstanding selective chiral recognition (alpha) was observed as 2.61 for L-enantiomer of AA. The sensitivity (S) and the limit of detection (LOD) values for L-AA were calculated as 0.0226 Hz/mu M and 0.63 mu M, respectively. Furthermore, the sorption behavior and mechanism of AA onto compound 6 film were evaluated and the sorption data exhibited a good correlation with the Freundlich isotherm models. The maximum uptake of L-AA by the sensor was found as 5895.76 mg/g. In conclusion, chiral recognition of AA enantiomers as real-time, sensitive, selective and effective was performed by a calixarene derivative coated QCM sensor. | en_US |
dc.description.sponsorship | Scientific and Technological Research Council of Turkey (TUBITAK-Grant)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [115Z249]; Research Foundation of the Selcuk UniversitySelcuk University [17201035] | en_US |
dc.description.sponsorship | We thank the Scientific and Technological Research Council of Turkey (TUBITAK-Grant Number 115Z249) and the Research Foundation of the Selcuk University (SUBAP-Grant Number 17201035) and for financial support of this work produced from Merve Akpinar's M.Sc. Thesis. | en_US |
dc.language.iso | en | en_US |
dc.publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE | en_US |
dc.relation.ispartof | ANALYTICAL BIOCHEMISTRY | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Ascorbic Acid | en_US |
dc.subject | Calixarene | en_US |
dc.subject | Chiral Detection | en_US |
dc.subject | Quartz Crystal Microbalance Sensor | en_US |
dc.subject | Sensing | en_US |
dc.subject | Quartz-Crystal Microbalance | en_US |
dc.subject | Coated Qcm Sensors | en_US |
dc.subject | Ionic Liquid | en_US |
dc.subject | Gas Sensor | en_US |
dc.subject | Uric-Acid | en_US |
dc.subject | Recognition | en_US |
dc.subject | Bearing | en_US |
dc.subject | Adsorption | en_US |
dc.subject | Calixarene | en_US |
dc.subject | Dopamine | en_US |
dc.title | A phenyl glycinol appended calix[4]arene film for chiral detection of ascorbic acid on gold surface | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1016/j.ab.2019.113373 | - |
dc.identifier.pmid | PubMed: 31344347 | en_US |
dc.identifier.scopus | 2-s2.0-85069737340 | en_US |
dc.department | Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümü | en_US |
dc.authorid | Tabakci, Mustafa/0000-0003-2941-2191 | - |
dc.authorwosid | Tabakci, Mustafa/AAJ-1071-2021 | - |
dc.authorwosid | A–zAelik, Egemen/ABB-7367-2021 | - |
dc.authorwosid | Ozcelik, Egemen/AAW-3887-2021 | - |
dc.authorwosid | Temel, Farabi/AAR-6170-2021 | - |
dc.identifier.volume | 583 | en_US |
dc.identifier.wos | WOS:000518158600002 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 57220340973 | - |
dc.authorscopusid | 57170366300 | - |
dc.authorscopusid | 8587997700 | - |
dc.authorscopusid | 57193853982 | - |
dc.authorscopusid | 6506600394 | - |
dc.identifier.scopusquality | Q2 | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | embargo_20300101 | - |
item.languageiso639-1 | en | - |
item.openairetype | Article | - |
item.fulltext | With Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.dept | 02.01. Department of Chemical Engineering | - |
crisitem.author.dept | 02.01. Department of Chemical Engineering | - |
Appears in Collections: | Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collections Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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1-s2.0-S0003269719300739-main.pdf Until 2030-01-01 | 1.09 MB | Adobe PDF | View/Open Request a copy |
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