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https://hdl.handle.net/20.500.13091/6265
Title: | Nanocomposites based on MWCNT and nanoclay: Effect of acrylated epoxidized soybean oil on curing and composite properties | Authors: | Işık, Murat Ahmetli, Gülnare |
Keywords: | Epoxy resin AESO Modification Nanocomposite Thermal curing UV curing Walled Carbon Nanotubes Dynamic-Mechanical Properties Electrical-Conductivity Epoxy-Resin Surface Modification Thermal-Properties Uv Functionalization Photopolymerization Montmorillonite |
Publisher: | Elsevier | Abstract: | UV and thermal-curing hybrid epoxy adhesives are generally developed with a combination of epoxy acrylates and thermal-curing epoxy resin. This study modified bisphenol-A type epoxy resin (ER) with acrylated epoxidized industrial crop soybean oil (AESO) to obtain a dual-curable epoxy system. Hydroxylated multi-walled carbon nanotube (MWCNTOH) and montmorillonite-type nanoclay (NC) first was used as nano reinforcement in this system. Both thermal and UV-curing were applied to composites. Tensile and hardness tests, thermogravimetric analysis (TGA), and four-point probe electrical conductivity measurements were used for the nano- composite characterization. Although (UV+thermal) curing increased the thermal strength of the nanocomposites, it caused a decrease in their electrical conductivity and moisture absorption. The highest tensile strength values were obtained as 107 MPa and 97 MPa for thermally cured 1.5 wt% MWCNTOH and 2 wt% NC composites, respectively. The effect of the AESO ratio on UV curing of nanocomposites was investigated and 10 % was found to be the most suitable. MWCNTOH composites also exhibited the highest electrical conductivity with a percolation threshold of 1.5 wt%. The effect of hydrothermal aging on thermal and electrical conductivity properties showed that only T5 and T10 values of thermally or (UV+thermally) cured MWCNTOH and NC composites decreased, T50 values did not change significantly. | URI: | https://doi.org/10.1016/j.indcrop.2024.119421 https://hdl.handle.net/20.500.13091/6265 |
ISSN: | 0926-6690 1872-633X |
Appears in Collections: | Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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