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https://hdl.handle.net/20.500.13091/618
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DC Field | Value | Language |
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dc.contributor.author | Gil-Escrig, Lidon | - |
dc.contributor.author | Dreessen, Chris | - |
dc.contributor.author | Kaya, İsmail Cihan | - |
dc.contributor.author | Kim, Beom-Soo | - |
dc.contributor.author | Palazon, Francisco | - |
dc.contributor.author | Sessolo, Michele | - |
dc.contributor.author | Bolink, Henk J. | - |
dc.date.accessioned | 2021-12-13T10:29:44Z | - |
dc.date.available | 2021-12-13T10:29:44Z | - |
dc.date.issued | 2020 | - |
dc.identifier.issn | 2380-8195 | - |
dc.identifier.uri | https://doi.org/10.1021/acsenergylett.0c01473 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.13091/618 | - |
dc.description.abstract | Preparation of black formamidinium lead iodide (FAPbI(3)) requires high-temperature annealing and the incorporation of smaller A-site cations, such as methylammonium (MA(+)), cesium, or rubidium. A major advantage of vacuum processing is the possibility to deposit perovskite films at room temperature (RT), without any annealing step. Here we demonstrate stabilization of the cubic perovskite phase at RT, in a three-source co-sublimation method. We found that the MA(+) incorporation is a self-limiting process, where the amount of MA(+) which is incorporated in the perovskite is essentially unvaried with increasing MAI deposition rate. In this way a phase-pure, cubic perovskite with a bandgap of 1.53 eV can be obtained at room temperature. When used in fully vacuum-processed perovskite solar cells, PCEs up to 18.8% are obtained. Despite the presence of MA(+), the solar cells were found to be thermally stable and maintained 90% of their initial efficiency after 1 month of continuous operation. | en_US |
dc.description.sponsorship | European Research Council (ERC) under the European UnionEuropean Research Council (ERC) [834431, 763977]; Spanish Ministry of Science, Innovation and Universities (MICIU) [MAT2017-88821-R, RTI2018-095362-A-I00, PCI2019-111829-2, EQC2018-004888-P]; Comunitat Valenciana [EQC2018-004888-P, IDIFEDER/2018/061]; TUBITAK -International Doctoral Research Fellowship ProgrammeTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [2214-A]; la Caixa FoundationLa Caixa Foundation [100010434, LCF/BQ/DI19/11730020]; MICIU | en_US |
dc.description.sponsorship | The research leading to these results has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation programme Grant Agreement No. 834431 and under Grant Agreement No. 763977 of the PERTPV project, the Spanish Ministry of Science, Innovation and Universities (MICIU, MAT2017-88821-R, RTI2018-095362-A-I00, PCI2019-111829-2, EQC2018-004888-P and EQC2018-004888-P) and the Comunitat Valenciana (IDIFEDER/2018/061, EQC2018-004888-P). I.C.K. thanks TUBITAK 2214-A -International Doctoral Research Fellowship Programme for supporting his research at ICMol. C.D. acknowledges that the project that gave rise to these results received the support of a fellowship from la Caixa Foundation (ID 100010434, code LCF/BQ/DI19/11730020). M.S. and F.P. acknowledge the MICIU for their RyC and JdC contracts, respectively. | en_US |
dc.language.iso | en | en_US |
dc.publisher | AMER CHEMICAL SOC | en_US |
dc.relation.ispartof | ACS ENERGY LETTERS | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Formamidinium Lead Iodide | en_US |
dc.subject | Phase | en_US |
dc.subject | Methylammonium | en_US |
dc.subject | Junction | en_US |
dc.subject | Cation | en_US |
dc.subject | Layers | en_US |
dc.subject | Limit | en_US |
dc.title | Efficient Vacuum-Deposited Perovskite Solar Cells with Stable Cubic FA(1)(-x)MA(x)PbI(3) | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1021/acsenergylett.0c01473 | - |
dc.identifier.scopus | 2-s2.0-85092298175 | en_US |
dc.department | Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümü | en_US |
dc.authorid | KAYA, Ismail Cihan/0000-0003-0773-0391 | - |
dc.authorwosid | KAYA, Ismail Cihan/L-8046-2019 | - |
dc.authorwosid | Sessolo, Michele/P-8911-2014 | - |
dc.authorwosid | Bolink, Henk/L-7618-2014 | - |
dc.authorwosid | Palazon, Francisco/K-3094-2019 | - |
dc.identifier.volume | 5 | en_US |
dc.identifier.issue | 9 | en_US |
dc.identifier.startpage | 3053 | en_US |
dc.identifier.endpage | 3061 | en_US |
dc.identifier.wos | WOS:000571642600036 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 56190707200 | - |
dc.authorscopusid | 57194021538 | - |
dc.authorscopusid | 56966296500 | - |
dc.authorscopusid | 56456858000 | - |
dc.authorscopusid | 56140657100 | - |
dc.authorscopusid | 18134748900 | - |
dc.authorscopusid | 8542734300 | - |
dc.identifier.scopusquality | Q1 | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.languageiso639-1 | en | - |
item.openairetype | Article | - |
item.fulltext | With Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.dept | 02.11. Department of Metallurgical and Materials Engineering | - |
Appears in Collections: | Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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File | Size | Format | |
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gil-escrig2020.pdf | 4.73 MB | Adobe PDF | View/Open |
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