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https://hdl.handle.net/20.500.13091/366
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DC Field | Value | Language |
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dc.contributor.author | Ceyhan, Ayhan Abdullah | - |
dc.contributor.author | Edebali, Serpil | - |
dc.contributor.author | Fangaj, Enis | - |
dc.date.accessioned | 2021-12-13T10:24:06Z | - |
dc.date.available | 2021-12-13T10:24:06Z | - |
dc.date.issued | 2020 | - |
dc.identifier.issn | 0360-3199 | - |
dc.identifier.issn | 1879-3487 | - |
dc.identifier.uri | https://doi.org/10.1016/j.ijhydene.2020.07.259 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.13091/366 | - |
dc.description | 4th International Hydrogen Technologies Congress (IHTEC) -- JUN 20-23, 2019 -- Trakya Univ, Edirne, TURKEY | en_US |
dc.description.abstract | Hydrogen production via chemical processes has gained great attention in recent years. In this study, Co-based complex catalyst obtained by adsorption of Co metal to Amberlite IRC-748 resin and Diaion CR11 were tested for hydrogen production from alkaline NaBH4 via hydrolysis process. Their catalytic activity and microstructure were investigated. Process parameters affecting the catalytic activity, such as NaOH concentration, Co percentage and catalyst amount, as well as NaBH4 concentration and temperature were investigated. Furthermore, characteristics of these catalysts were carried out via SEM, XRD and FT-IR analysis. Hydrogen production rates equal to 211 and 221 ml min(-1) gcat(-1) could be obtained with Amberlite IRC-748 resin and Diaion CR11 Co based complex catalysts, respectively. The activation energies of the catalytic hydrolysis reaction of NaBH4 were calculated as 46.9 and 59.42 kJ mol(-1) for Amberlite IRC-748 resin and Diaion CR11 based catalysts respectively kJ mol(-1) from the system consisting of 3% Co, 10 wt% NaBH4 and 7 wt% NaOH as well as 50 mg catalyst dosage. It can be concluded that Co-based resins as catalysts for hydrogen production is an effective alternative to other catalysts having higher rate. (C) 2020 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC. | en_US |
dc.language.iso | en | en_US |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | en_US |
dc.relation.ispartof | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Cobalt Complex Catalyst | en_US |
dc.subject | Sodium Borohydride Hydrolysis | en_US |
dc.subject | Hydrogen Generation | en_US |
dc.subject | Resins | en_US |
dc.subject | Sodium-Borohydride Solution | en_US |
dc.subject | Highly Efficient Catalyst | en_US |
dc.subject | B Catalyst | en_US |
dc.subject | Hydrolysis Reaction | en_US |
dc.subject | Reusable Catalyst | en_US |
dc.subject | Complex Catalyst | en_US |
dc.subject | Supported Cobalt | en_US |
dc.subject | Nanoparticles | en_US |
dc.subject | Ru | en_US |
dc.subject | Methanolysis | en_US |
dc.title | A study on hydrogen generation from NaBH4 solution using Co-loaded resin catalysts | en_US |
dc.type | Conference Object | en_US |
dc.identifier.doi | 10.1016/j.ijhydene.2020.07.259 | - |
dc.identifier.scopus | 2-s2.0-85089828102 | en_US |
dc.department | Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümü | en_US |
dc.authorwosid | Ceyhan, Ayhan Abdullah/AAG-4179-2019 | - |
dc.identifier.volume | 45 | en_US |
dc.identifier.issue | 60 | en_US |
dc.identifier.startpage | 34761 | en_US |
dc.identifier.endpage | 34772 | en_US |
dc.identifier.wos | WOS:000609161600019 | en_US |
dc.relation.publicationcategory | Konferans Öğesi - Uluslararası - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 8959388100 | - |
dc.authorscopusid | 35760236600 | - |
dc.authorscopusid | 57216414045 | - |
item.languageiso639-1 | en | - |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
item.openairetype | Conference Object | - |
item.grantfulltext | embargo_20300101 | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.dept | 02.01. Department of Chemical Engineering | - |
crisitem.author.dept | 02.01. Department of Chemical Engineering | - |
Appears in Collections: | Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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1-s2.0-S0360319920329347-main.pdf Until 2030-01-01 | 1.77 MB | Adobe PDF | View/Open Request a copy |
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