Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.13091/2921
Title: Nickel adsorption from waters onto Fe3O4/sugar beet pulp nanocomposite
Authors: Sadat, Sayed Mohammad Osman
Küçükçongar, Sezen
Türkyılmaz, Mehmet
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Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Çevre Mühendisliği Bölümü
Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Çevre Mühendisliği Bölümü
Keywords: Ni(II) removal
sugar beet pulp
industrial waste
nanocomposite
magnetic adsorbent
waste reuse
Bagasse Fly-Ash
Aqueous-Solution
Metal-Ions
Toxic Metal
Orange Peel
Removal
Waste
Ni(Ii)
Green
Nanoparticles
Issue Date: 2022
Publisher: Taylor & Francis Inc
Abstract: In this study the magnetic nanocomposite material was synthesized with Fe3O4 impregnated to sugar beet pulp using chemical precipitation technique. Ni(II) removal performance of magnetic nanocomposite was investigated under different environmental conditions such as contact time, adsorbent dose, pH, initial heavy metal concentration, etc. The experimental studies have shown that, 81.2% Ni(II) removal efficiency was achieved at optimal conditions (25 mg/L initial Ni(II) concentration at 40 minute contact time, 200 rpm shaking speed, 5 g/L nanocomposite dose and pH 6.6). Freundlich and Langmuir isotherm experiments were performed and correlation coefficients were determined as 94.5% and 99.4%, respectively. The maximum adsorption capacity of material was achieved as 9.36 mg/g. These findings indicate that the adsorption that takes place is a monolayer process. The results of the pseudo-second order kinetic model (R-2 = 0.9947) indicate the chemisorptions process is used for Ni(II) removal using the electrostatic interaction. Thermodynamic studies illustrated that Ni(II) adsorption onto nanocomposite are exothermic and causes a decrease in the entropy. The adsorption of Ni(II) ions is non-spontaneous except for at low temperature and low initial concentrations. Nanocomposite characterization was illuminated with XRD, FT-IR, BET, TGA, TEM, SEM/EDX analysis. NOVELTY STATEMENT In this study, it was aimed to synthesis new adsorbent using sugar beet pulp together with Fe3O4 under suitable conditions, obtain a magnetic nanocomposite, and examine the reusability and recovery properties of the produced material. The use of industrial wastes as an adsorbent material provides both a solution to the problem of the removal of wastes and a reuse method for the use of wastes as a low cost adsorbent for a useful purpose. Therefore, it has two advantages: There is a need to investigate the feasibility of investigating all possible industry-based cheap adsorbent sources as well as the removal of heavy metals for the production of a reliable and harmless adsorbent.
URI: https://doi.org/10.1080/15226514.2022.2093832
https://hdl.handle.net/20.500.13091/2921
ISSN: 1522-6514
1549-7879
Appears in Collections:Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collections
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections

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