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https://hdl.handle.net/20.500.13091/2448
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zeidan, Hani | - |
dc.contributor.author | Yurdakul, Merve | - |
dc.contributor.author | Martı, Mustafa Esen | - |
dc.date.accessioned | 2022-05-23T20:22:44Z | - |
dc.date.available | 2022-05-23T20:22:44Z | - |
dc.date.issued | 2022 | - |
dc.identifier.issn | 0021-9568 | - |
dc.identifier.issn | 1520-5134 | - |
dc.identifier.uri | https://doi.org/10.1021/acs.jced.1c00633 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.13091/2448 | - |
dc.description.abstract | Separation of carboxylic acids from dilute aqueous solutions is a challenging problem, and reactive extraction has been examined as an attractive alternative for this process. This study aims to investigate the reactive extraction of pimelic acid (PA) using tri-n-octylamine (TOA) in 1-hexanol, 1-octanol, xylene, and n-hexane. The highest extraction efficiency (E (%)) and distribution coefficient (K-D) were obtained at pH 3, which is the unadjusted pH of the aqueous PA solution. Extractive efficiency varied inversely with temperature and initial PA concentration but increased with the increase in TOA amount. The highest E (%) and K-D values (98.5% and 67.2, respectively) were obtained with 1-hexanol at initial TOA and PA concentrations of 0.2700 and 0.0375 mol/kg, respectively. The process was modeled using multilinear regression, and the model closely correlated with experimental results for all organic solvents tested. | en_US |
dc.description.sponsorship | Konya Technical University; Scientific Research Projects (BAP) Coordination Unit [17401008] | en_US |
dc.description.sponsorship | The authors acknowledge Konya Technical University for the funding through the Scientific Research Projects (BAP) Coordination Unit under Grant Number 17401008. The authors also thank Prof. Dr. Sencer Buzrul for contributions to the modelling part of the study. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Amer Chemical Soc | en_US |
dc.relation.ispartof | Journal Of Chemical And Engineering Data | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Response-Surface Methodology | en_US |
dc.subject | Excess Molar Volumes | en_US |
dc.subject | Aqueous-Solutions | en_US |
dc.subject | Carboxylic-Acids | en_US |
dc.subject | Butyl Phosphate | en_US |
dc.subject | Levulinic Acid | en_US |
dc.subject | Lactic-Acid | en_US |
dc.subject | Aliquat 336 | en_US |
dc.subject | Optimization | en_US |
dc.subject | Fermentation | en_US |
dc.title | Separation of Pimelic Acid Using Tri-n-octylamine in Various Organic Solvents by Reactive Extraction: Equilibrium and Modeling | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1021/acs.jced.1c00633 | - |
dc.identifier.scopus | 2-s2.0-85121050317 | en_US |
dc.department | Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümü | en_US |
dc.authorid | MARTI, Mustafa/0000-0002-9829-0602 | - |
dc.authorid | Zeidan, Hani/0000-0002-5891-3887 | - |
dc.identifier.volume | 67 | en_US |
dc.identifier.issue | 1 | en_US |
dc.identifier.startpage | 182 | en_US |
dc.identifier.endpage | 191 | en_US |
dc.identifier.wos | WOS:000759320200021 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.scopusquality | Q2 | - |
item.grantfulltext | embargo_20300101 | - |
item.languageiso639-1 | en | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.openairetype | Article | - |
item.cerifentitytype | Publications | - |
crisitem.author.dept | 02.01. Department of Chemical Engineering | - |
Appears in Collections: | Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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File | Size | Format | |
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acs.jced.1c00633.pdf Until 2030-01-01 | 1.58 MB | Adobe PDF | View/Open Request a copy |
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