Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.13091/2414
Title: Investigation of Endosulfan Removal and Metabolite Formation by Photocatalysis Process under UV-C Light Source Using Taguchi Experimental Design Program
Authors: Türkyılmaz, Mehmet
Küçükcongar, Sezen
Keywords: Magnetic separation
reusability
pesticide removal
photocatalysis
Degradation
Water
Tio2
Oxidation
Membranes
Issue Date: 2022
Publisher: Taylor & Francis Ltd
Abstract: In this study, the efficiency of the synthesised Ag/TiO2/Fe3O4 catalyst in the removal of endosulfan and metabolite formation by the photocatalysis process, the effect, and optimisation of the ambient conditions were investigated under UV-C light source. Photocatalysis process for endosulfan removal and degradation to metabolites was optimised with Taguchi experimental design method and the results were evaluated statistically by analysis of variance. Light intensity, amount of catalyst, initial endosulfan concentration, pH, and time were chosen as controllable parameters. The highest S/N ratios on the based on parameters were obtained at 27 W light power, pH 4, 0.5 g/L catalyst amount, 60 min reaction time and 4 mg/L initial endosulfan concentration. Since these values, at which the highest removal rate will be achieved, were not found in the experimental design, a confirmation experiment was performed and the removal was obtained as 93.2%. It was found that the most effective parameters on the removal efficiency were the initial endosulfan concentration and pH, respectively. As a result of analysis of variance, F-critical values showed that the effects of light power, catalyst amount and reaction time on endosulfan removal were not statistically significant. When the P values are examined, it is seen that there is a significant difference between the initial endosulfan concentration and the levels of the pH factor for endosulfan removal. No formations of endosulfan sulphate, endosulfan ether, and endosulfan lactone were observed at high concentrations while endosulfan was removed.
URI: https://doi.org/10.1080/03067319.2021.2025227
https://hdl.handle.net/20.500.13091/2414
ISSN: 0306-7319
1029-0397
Appears in Collections:Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections

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