Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.13091/1583
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dc.contributor.authorYılmaz, Kurtuluş-
dc.contributor.authorGürsoy, Mehmet-
dc.contributor.authorKaraman, Mustafa-
dc.date.accessioned2021-12-13T10:41:34Z-
dc.date.available2021-12-13T10:41:34Z-
dc.date.issued2021-
dc.identifier.issn0743-7463-
dc.identifier.urihttps://doi.org/10.1021/acs.langmuir.0c03437-
dc.identifier.urihttps://hdl.handle.net/20.500.13091/1583-
dc.description.abstractThis study demonstrates the coating of a transparent and robust organic thin film having an excellent hydrophilicity-based antifogging property by an initiated chemical vapor deposition (iCVD) method. iCVD was able to synthesize linear and cross-liked poly(acrylic acid) (PAA) from the vapors of acrylic acid (AA) and ethylene glycol dimethacrylate (EGDMA) using tert-butyl peroxide (TBPO) as an initiator. High deposition rates of up to 35 nm/min were observed at low deposition temperatures. It was possible to control the quantity of comonomers in the as-deposited films by adjusting the partial pressure of the EGDMA cross-linking agent. The effect of the EGDMA partial pressure on chemical structure was studied using Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) techniques. FTIR and XPS spectra of the as-deposited films showed the complete retention of the monomer functionality during iCVD. Hydrophilicities and large-area uniformity of the coatings were revealed using water contact angle measurements. The as-deposited PAA film was the most hydrophilic with a water contact angle (WCA) of 7.0 degrees, while cross-linking with EGDMA increased the WCA values by up to 51.7 degrees. Results of various tests, which were based on exposing the coated surfaces to artificial fog and hot water vapor, showed the excellent antifogging property of the coatings. Films were never fogged upon extensive and long-term exposure (2 months) to humid air.en_US
dc.description.sponsorshipKonya Technical University Scientific Research Foundation [201016003]en_US
dc.description.sponsorshipThis study was supported by the Konya Technical University Scientific Research Foundation (project number 201016003).en_US
dc.language.isoenen_US
dc.publisherAMER CHEMICAL SOCen_US
dc.relation.ispartofLANGMUIRen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleVapor Deposition of Transparent Antifogging Polymeric Nanocoatingsen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/acs.langmuir.0c03437-
dc.identifier.pmidPubMed: 33507758en_US
dc.identifier.scopus2-s2.0-85102090431en_US
dc.departmentFakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.authoridYilmaz, Kurtulus/0000-0002-6813-6153-
dc.identifier.volume37en_US
dc.identifier.issue5en_US
dc.identifier.startpage1941en_US
dc.identifier.endpage1947en_US
dc.identifier.wosWOS:000618892400030en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.authorscopusid57210426921-
dc.authorscopusid57208454280-
dc.authorscopusid35269112600-
dc.identifier.scopusqualityQ1-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
item.languageiso639-1en-
item.openairetypeArticle-
item.grantfulltextembargo_20300101-
item.cerifentitytypePublications-
crisitem.author.dept02.01. Department of Chemical Engineering-
crisitem.author.dept02.01. Department of Chemical Engineering-
Appears in Collections:Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collections
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections
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