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https://hdl.handle.net/20.500.13091/1376
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Temel, Farabi | - |
dc.contributor.author | Erdemir, Serkan | - |
dc.contributor.author | Tabakcı, Begüm | - |
dc.contributor.author | Akpınar, Merve | - |
dc.contributor.author | Tabakcı, Mustafa | - |
dc.date.accessioned | 2021-12-13T10:38:49Z | - |
dc.date.available | 2021-12-13T10:38:49Z | - |
dc.date.issued | 2019 | - |
dc.identifier.issn | 1618-2642 | - |
dc.identifier.issn | 1618-2650 | - |
dc.identifier.uri | https://doi.org/10.1007/s00216-019-01705-5 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.13091/1376 | - |
dc.description.abstract | We describe the synthesis of new chiral calix[4]arene derivatives having (R)-1-phenylethylamine, (S)-1-phenylethylamine, (R)-2-phenylglycinol, and (S)-2-phenylglycinol moieties, and chiral recognition studies for enantiomers of some selected -amino acid derivatives such as alanine, phenylalanine, serine, and tryptophan using a quartz crystal microbalance (QCM). Initial experiments indicated that the highest selective chiral recognition factor was 1.42 for alanine enantiomers. The sensitivity, limit of detection, and time constant for l-alanine were calculated as 0.028 Hz/M, 60.9 M, and 36.2 s, respectively. The results indicated that real-time, sensitive, selective, and effective chiral recognition of alanine enantiomers was achieved with a QCM sensor coated with a chiral calix[4]arene derivative having (R)-2-phenylglycinol moieties. | en_US |
dc.description.sponsorship | Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [115Z249]; Research Foundation of Selcuk University (SUBAP grant), Konya, Turkey [16401003] | en_US |
dc.description.sponsorship | We thank the Technical Research Council of Turkey (TUBITAK grant number 115Z249) and the Research Foundation of Selcuk University (SUBAP grant number 16401003), Konya, Turkey, and for financial support of this work produced from FT's Ph.D. thesis. | en_US |
dc.language.iso | en | en_US |
dc.publisher | SPRINGER HEIDELBERG | en_US |
dc.relation.ispartof | ANALYTICAL AND BIOANALYTICAL CHEMISTRY | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Amino Acid | en_US |
dc.subject | Calixarene | en_US |
dc.subject | Alanine | en_US |
dc.subject | Chiral Recognition | en_US |
dc.subject | Quartz Crystal Microbalance Sensor | en_US |
dc.subject | Qcm Sensors | en_US |
dc.subject | Resonant-Frequency | en_US |
dc.subject | Discrimination | en_US |
dc.subject | Immunosensor | en_US |
dc.subject | Optimization | en_US |
dc.subject | Interface | en_US |
dc.subject | Array | en_US |
dc.title | Selective chiral recognition of alanine enantiomers by chiral calix[4]arene coated quartz crystal microbalance sensors | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1007/s00216-019-01705-5 | - |
dc.identifier.pmid | PubMed: 30931505 | en_US |
dc.identifier.scopus | 2-s2.0-85064271610 | en_US |
dc.department | Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümü | en_US |
dc.authorid | Temel, Farabi/0000-0002-5502-8647 | - |
dc.authorwosid | Temel, Farabi/AAR-6170-2021 | - |
dc.authorwosid | Tabakci, Mustafa/AAJ-1071-2021 | - |
dc.authorwosid | Erdemir, Serkan/AAH-1504-2019 | - |
dc.identifier.volume | 411 | en_US |
dc.identifier.issue | 12 | en_US |
dc.identifier.wos | WOS:000464948100021 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 57170366300 | - |
dc.authorscopusid | 13610351500 | - |
dc.authorscopusid | 8587997700 | - |
dc.authorscopusid | 57220340973 | - |
dc.authorscopusid | 6506600394 | - |
dc.identifier.scopusquality | Q1 | - |
item.openairetype | Article | - |
item.languageiso639-1 | en | - |
item.grantfulltext | embargo_20300101 | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
crisitem.author.dept | 02.01. Department of Chemical Engineering | - |
crisitem.author.dept | 02.01. Department of Chemical Engineering | - |
Appears in Collections: | Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collections Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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