Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.13091/1184
Title: Nano-ZrO2/TiO2 Impregnated Orange Wood Sawdust and Peach Stone Shell Adsorbents for Cr (VI) Removal
Authors: Parlayıcı, Şerife
Sezer, Kübra Tuna
Pehlivan, Erol
Keywords: Cr (Vi) Removal
Kinetics
Orange Wood Sawdust
Peach Stone Shell
Zro2-Tio2 Nanoparticles
Adsorption Process
Aqueous-Solutions
Hexavalent Chromium
Cr(Vi)
Adsorption
Reduction
Waste
Issue Date: 2020
Publisher: BENTHAM SCIENCE PUBL LTD
Abstract: Background: In this work, Cr (VI) adsorption on nano-ZrO2 circle dot TiO2 impregnated orange wood sawdust (Zr circle dot Ti/OWS) and nano-ZrO2 circle dot TiO2 impregnated peach stone shell (Zr circle dot Ti/PSS) was investigated by applying different adsorption parameters such as Cr (VI) concentrations, contact time, adsorbent dose, and pH for all adsorbents. Methods: The adsorbents were characterized by SEM and FT-IR. The equilibrium status was achieved after 120 min of contact time and optimum pH value around 2 were determined for Cr (VI) adsorption. Adsorption data in the equilibrium is well-assembled by the Langmuir model during the adsorption process. Results: Langmuir isotherm model showed a maximum adsorption value of OWS: 21.65 mg/g and Zr circle dot Ti/OWS: 27.25 mg/g. The same isotherm displayed a maximum adsorption value of PSS: 17.64 mg/g, and Zr circle dot Ti/PSS: 31.15 mg/g. Pseudo-second-order kinetic models (R-2=0.99) were found to be the best models for describing the Cr (VI) adsorption reactions. Conclusion: Thermodynamic parameters such as changes in Delta G degrees, Delta H degrees, and Delta S degrees have been estimated, and the process was found to be spontaneous.
URI: https://doi.org/10.2174/1573411015666191114143128
https://hdl.handle.net/20.500.13091/1184
ISSN: 1573-4110
1875-6727
Appears in Collections:Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections

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