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https://hdl.handle.net/20.500.13091/1094
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Özçelik, Egemen | - |
dc.contributor.author | Temel, Farabi | - |
dc.contributor.author | Erdemir, Serkan | - |
dc.contributor.author | Tabakcı, Begüm | - |
dc.contributor.author | Tabakcı, Mustafa | - |
dc.date.accessioned | 2021-12-13T10:34:40Z | - |
dc.date.available | 2021-12-13T10:34:40Z | - |
dc.date.issued | 2019 | - |
dc.identifier.issn | 1388-3127 | - |
dc.identifier.issn | 1573-1111 | - |
dc.identifier.uri | https://doi.org/10.1007/s10847-019-00892-z | - |
dc.identifier.uri | https://hdl.handle.net/20.500.13091/1094 | - |
dc.description.abstract | This article describes the enantiomeric discrimination properties of new chiral calix[4]arene derivatives bearing (S)-/(R)-1-phenylethylamine moieties (5a and 5b, respectively) towards the 1-phenylethylamine enantiomers on QCM surface. Initial experiments demonstrated that the 5b coated QCM sensor was the most effective sensing material for enantiomeric discrimination of (R)-/(S)-1-phenylethylamine by exhibiting much more sensing ability towards (R)-enantiomer than (S)-enantiomer. Sensitivity, detection limit and time constant of the 5b coated QCM sensor has been were calculated as 0.082 Hz/mu M, 2.7 mu M, and 319.2 s, respectively. Additionally, effects of calixarene content and different coating technique on enantiomeric discrimination, and Langmuir and Freundlich isotherms of the sensing results also were studied. As a result, it has been demonstrated that the coating of QCM sensor with a chiral calix[4]arene (5b) having (S)-1-phenylethylamine moieties provides substantially enantiomeric discrimination of 1-phenylethylamine enantiomers. | en_US |
dc.description.sponsorship | Technical Research Council of Turkey (TUBITAK-Grant) [115Z249]; Research Foundation of the Selcuk UniversitySelcuk University [16401003]; Konya, Turkey | en_US |
dc.description.sponsorship | We thank the Technical Research Council of Turkey (TUBITAK-Grant No. 115Z249) and the Research Foundation of the Selcuk University (SUBAP-Grant No. 16401003), Konya, Turkey and for financial support of this work produced from Egemen Ozcelik's M.Sc. Thesis. | en_US |
dc.language.iso | en | en_US |
dc.publisher | SPRINGER | en_US |
dc.relation.ispartof | JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 1-Phenylethylamine | en_US |
dc.subject | Organic Coatings | en_US |
dc.subject | Calixarene | en_US |
dc.subject | Enantiomeric Discrimination | en_US |
dc.subject | Quartz Crystal Microbalance Sensor | en_US |
dc.subject | Alpha-Phenylethylamine | en_US |
dc.subject | Secondary-Amines | en_US |
dc.subject | Biosensor | en_US |
dc.subject | Recognition | en_US |
dc.subject | Calixarenes | en_US |
dc.subject | Separation | en_US |
dc.subject | Sorption | en_US |
dc.subject | Surface | en_US |
dc.subject | Design | en_US |
dc.subject | Films | en_US |
dc.title | QCM sensors coated with calix[4]arenes bearing sensitive chiral moieties for chiral discrimination of 1-phenylethylamine enantiomers | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1007/s10847-019-00892-z | - |
dc.identifier.scopus | 2-s2.0-85071678055 | en_US |
dc.department | Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümü | en_US |
dc.authorid | Temel, Farabi/0000-0002-5502-8647 | - |
dc.authorwosid | Temel, Farabi/AAR-6170-2021 | - |
dc.authorwosid | Erdemir, Serkan/AAH-1504-2019 | - |
dc.authorwosid | Tabakci, Mustafa/AAJ-1071-2021 | - |
dc.authorwosid | A–zAelik, Egemen/ABB-7367-2021 | - |
dc.authorwosid | Ozcelik, Egemen/AAW-3887-2021 | - |
dc.identifier.volume | 95 | en_US |
dc.identifier.issue | 1-2 | en_US |
dc.identifier.startpage | 35 | en_US |
dc.identifier.endpage | 48 | en_US |
dc.identifier.wos | WOS:000485967900003 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 57193853982 | - |
dc.authorscopusid | 57170366300 | - |
dc.authorscopusid | 13610351500 | - |
dc.authorscopusid | 8587997700 | - |
dc.authorscopusid | 6506600394 | - |
dc.identifier.scopusquality | Q3 | - |
item.openairetype | Article | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.grantfulltext | embargo_20300101 | - |
item.languageiso639-1 | en | - |
crisitem.author.dept | 02.01. Department of Chemical Engineering | - |
crisitem.author.dept | 02.01. Department of Chemical Engineering | - |
Appears in Collections: | Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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s10847-019-00892-z.pdf Until 2030-01-01 | 2.51 MB | Adobe PDF | View/Open Request a copy |
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