Calixarene-Tethered Textile Fabric for the Efficient Removal of Hexavalent Chromium From Polluted Water

dc.contributor.author Özçelik, Egemen
dc.contributor.author Mercan Sevgili, Emine
dc.contributor.author Erdemir, Serkan
dc.contributor.author Karaman, Mustafa
dc.contributor.author Tabakcı, Mustafa
dc.date.accessioned 2021-12-13T10:34:40Z
dc.date.available 2021-12-13T10:34:40Z
dc.date.issued 2021
dc.description.abstract This study describes the tethering of dimethylamionomethyl bonded calixarene (DMAM-calixarene) onto cotton fabric surface functionalized with poly(glycidyl methacrylate) (PGMA) linker layer using initiated chemical vapor deposition (iCVD) technique and the efficient adsorption capability of DMAM-calixarene functional textiles for the toxic hexavalent chromium from polluted water. The characterization of DMAM-calixarene-tethered textile fabric was performed by FTIR and XPS spectroscopy. Cr(VI) solutions was passed over packed DMAMcalixarene-tethered textile fabric adsorbent and the highest adsorption was observed at pH 2 in dichromate anion form of COS. The regeneration and selectivity studies indicate that the DMAM-calixarene-tethered textile fabric has outstanding adsorbent features in used experimental conditions for hexavalent chromium. Moreover, it was observed that both H-bonding and electrostatic interactions were significant factors in the dichromate anion adsorption process. Thus, this study clearly revealed that any DMAM-calixarene-tethered textile fabric can be easily used as a selective hexavalent chromium capture filter in geographic regions lacking appropriate wastewater purification systems. en_US
dc.description.sponsorship Royal SocietyRoyal Society of LondonEuropean Commission [IC160021] en_US
dc.description.sponsorship This work was preliminarily supported financially by the Royal Society (International Collaboration Award reference IC160021). en_US
dc.identifier.doi 10.1016/j.colsurfa.2021.127045
dc.identifier.issn 0927-7757
dc.identifier.issn 1873-4359
dc.identifier.scopus 2-s2.0-85110111669
dc.identifier.uri https://doi.org/10.1016/j.colsurfa.2021.127045
dc.identifier.uri https://hdl.handle.net/20.500.13091/1092
dc.language.iso en en_US
dc.publisher ELSEVIER en_US
dc.relation.ispartof COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.subject Icvd en_US
dc.subject Water Pollution en_US
dc.subject Hexavalent Chromium en_US
dc.subject Textile en_US
dc.subject Calixarene en_US
dc.subject Adsorption en_US
dc.subject Chemical-Vapor-Deposition en_US
dc.subject Copolymer Thin-Films en_US
dc.subject Polymer Inclusion Membrane en_US
dc.subject Extraction Ability en_US
dc.subject Phenolic-Compounds en_US
dc.subject Arene Derivatives en_US
dc.subject Heavy-Metals en_US
dc.subject Lower Rim en_US
dc.subject Cr(Vi) en_US
dc.subject Adsorption en_US
dc.title Calixarene-Tethered Textile Fabric for the Efficient Removal of Hexavalent Chromium From Polluted Water en_US
dc.type Article en_US
dspace.entity.type Publication
gdc.author.id Ozcelik, Egemen/0000-0002-2604-4656
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gdc.author.wosid A–zAelik, Egemen/ABB-7367-2021
gdc.bip.impulseclass C4
gdc.bip.influenceclass C5
gdc.bip.popularityclass C4
gdc.coar.access metadata only access
gdc.coar.type text::journal::journal article
gdc.description.department Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümü en_US
gdc.description.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
gdc.description.scopusquality Q2
gdc.description.startpage 127045
gdc.description.volume 626 en_US
gdc.description.wosquality Q2
gdc.identifier.openalex W3174703478
gdc.identifier.wos WOS:000685970400005
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gdc.oaire.sciencefields 02 engineering and technology
gdc.oaire.sciencefields 0210 nano-technology
gdc.oaire.sciencefields 01 natural sciences
gdc.oaire.sciencefields 0104 chemical sciences
gdc.openalex.collaboration National
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gdc.opencitations.count 13
gdc.plumx.crossrefcites 4
gdc.plumx.mendeley 14
gdc.plumx.scopuscites 14
gdc.scopus.citedcount 14
gdc.virtual.author Tabakcı, Mustafa
gdc.virtual.author Mercan Sevgili, Emine
gdc.virtual.author Karaman, Mustafa
gdc.wos.citedcount 13
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