A Novel Core-Shell Fe3O4@SiO2/Co-Cr-B Magnetic Catalyst for Efficient and Reusable Hydrogen Evolution From NaBH4 Hydrolysis

Abstract

This study presents a novel core-shell magnetic catalyst, Fe3O4@SiO2/Co-Cr-B, engineered for efficient and reusable hydrogen generation from NaBH4 hydrolysis, offering significant advancement in sustainable hydrogen production technologies. The innovation lies in the synergistic integration of a magnetic Fe3O4@SiO2 core with a bimetallic Co-Cr-B shell, which enhances catalytic activity, structural stability, and facile magnetic recovery. Field emission scanning electron microscopy (FE-SEM) revealed a distinctive grape-like morphology resulting from nanoparticle agglomeration, which increased the surface area and active site accessibility. Transmission electron microscopy (TEM) confirmed a well-defined core-shell architecture with a uniform Co-Cr-B shell thickness of 40-50 nm and a consistent particle distribution. These structural features directly contribute to the catalyst's high hydrogen generation rate of 22.2 L gmetal(-1) min(-1) at 30 degrees C with a turnover frequency (TOF) of 2110.61 mol(H2) molcat(-1) h(-1). The catalyst demonstrated remarkable stability and maintained >90% of its initial activity after six consecutive reusability tests. These findings highlight the potential of this catalyst for large-scale hydrogen production and offer a promising route for industrial applications with improved efficiency and durability.