PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collections

Permanent URI for this collectionhttps://hdl.handle.net/20.500.13091/5

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Now showing 1 - 7 of 7

Citation - WoS: 50
Citation - Scopus: 55
Advanced Oxidation of Landfill Leachate: Removal of Micropollutants and Identification of By-Products
(ELSEVIER, 2021) Ateş, Havva; Argun, Mehmet Emin
Landfill leachate contains several macropollutants and micropollutants that cannot be removed efficiently by conventional treatment processes. Therefore, an advanced oxidation process is a promising step in post or pre-treatment of leachate. In this study, the effects of Fenton and ozone oxidation on the removal of 16 emerging micropollutants including polycyclic aromatic hydrocarbons (PAHs), phthalates, alkylphenols and pesticides were investigated. The Fenton and ozone oxidation of the leachate were performed with four (reaction time: 20-90 min, Fe(II) dose: 0.51-2.55 g/L, H2O2 dose: 5.1-25.5 g/L and pH: 3-5) and two (ozonation time: 10-130 min and pH: 4-10) independent variables, respectively. Among these operating conditions, reaction time played more significant role (p-value < 0.05) in eliminating di-(2-Ethylhexyl) phthalate, 4-nonylphenol and 4-tert-octylphenol for both processes. The results showed that Fenton and ozone oxidation processes had a high degradation potential for micropollutants except for the PAHs including four and more rings. Removal efficiencies of micropollutants by ozone and Fenton oxidation were determined in the range of 5-100%. Although the removal efficiencies of chemical oxygen demand (COD) and some micropollutants such as phthalates were found much higher in the Fenton process than ozonation, the degradation products occurred during the Fenton oxidation were a higher molecular weight. Moreover, the oxidation intermediates for the both processes were found as mainly benzaldehyde, pentanoic acid and hydro cinnamic acid as well as derivatives of naphthalenone and naphthalenediol. Also, acid ester with higher molecular weight, naphthalene-based and phenolic compounds were detected in the Fenton oxidation.
Citation - WoS: 36
Citation - Scopus: 43
Comparison of Advanced Biological Treatment and Nature-Based Solutions for the Treatment of Pharmaceutically Active Compounds (phacs): a Comprehensive Study for Wastewater and Sewage Sludge
(ELSEVIER, 2021) Nas, Bilgehan; Dolu, Taylan; Argun, Mehmet Emin; Yel, Esra; Ateş, Havva; Koyuncu, Serdar
Passing of pharmaceutical residues into environment in an uncontrolled manner as a result of continuous increase in drug consumption across the globe has become a threatening problem for the ecosystems and almost all living creatures. In this study, diclofenac (DCF), carbamazepine (CBZ), 17 beta-estradiol (17 beta-E2) and 17 alpha ethynylestradiol (EE2) belonging to different therapeutic classes were investigated simultaneously in advanced biological treatment and nature-based treatments during 12-months sampling campaign. In this context, behavior patterns of pharmaceutically active compounds (PhACs) throughout the both wastewater and sludge lines in advanced biological wastewater treatment plant (WWTP), wastewater stabilization pond (WSP) and constructed wetland (CW) were discussed in detail based on each treatment processes seasonally. Furthermore, statistically evaluated data obtained in full-scale WWTPs were compared with each other in order to determine the valid removal mechanisms of these pharmaceutical compounds. While DCF and CBZ were detected very intensively both in the wastewater and sludge lines of the investigated WWTPs, steroid hormones,17 beta-E2 and EE2, were determined below the LOQ value in general. Annual average removal efficiencies achieved in studied WWTPs for DCF ranged between & minus;23.3% (in CW) and 75.2% (in WSP), while annual average removal rates obtained for CBZ varied between & minus;20.7% (in advanced biological treatment) and 10.0% (in CW). It has been found that DCF was highly affected by different wastewater treatment processes applied in the WWTPs compared to CBZ which showed extraordinary resistance to all different treatment processes. Although calculated in different rates for each compounds, biodegradation/biotransformation and sorption onto sewage sludge were determined as the main removal mechanisms for PhACs in plants. Although showed a similar behavior in the sludge dewatering unit (decanter) present in the advanced biological WWTP, quite different behaviors ob-served in the anaerobic digester for DCF (up to 15% decrease) and CBZ (up to 95% increase). Sorption and desorp-tion behaviors of DCF and CBZ were also evaluated in the sludge treatment processes found in advanced biological WWTP. Percentages of originated extra annual average of pharmaceutical loads were calculated as 0.64% and 0.90% for DCF and CBZ, respectively in the advanced biological WWTP due to the sidestream caused by the sludge dewatering unit. (c) 2021 Elsevier B.V. All rights reserved.
Citation - WoS: 5
Citation - Scopus: 7
Estimation of the Risk of Work-Related Accidents for Underground Hard Coal Mine Workers by Logistic Regression
(TAYLOR & FRANCIS LTD, 2022) Bilim, Niyazi; Bilim, Atiye
Coal mining has the most risk in all of the mining sectors. Hence, in this sector, most work accidents encountered are intensive. The demographic characteristics of workers affect the occurrence of occupational accidents. This study aims to develop an equation that predicts workday loss by analyzing the relationship between workers' demographic characteristics and having an accident with workday loss. In this study, work-related accidents between 2014 and 2019 in underground hard coal mines in Turkey were analyzed using logistic regression analysis. An equation is derived that estimates the workday loss with the characteristics of workers in hard coal mines. With the equation derived in this study, employers can determine the potential for work accidents according to the demographic characteristics of the workers and serious work accidents will be prevented. Therefore, proactive solutions can be produced by applying the methods used in this study to different industries.
Citation - WoS: 8
Citation - Scopus: 9
An Insight on the Impact of Covid-19 on the Global and Turkish Mining Industry
(Ios Press, 2022) Kekeç, Bilgehan; Bilim, Niyazi; Ghiloufi, Dhikra
BACKGROUND: COVID-19 affected numerous industries and the mining industry has not been immune to the adverse impacts caused by the pandemic. OBJECTIVE: This study examines the importance of the mining industry and its benefits to the economy of the producing countries. The paper also gives an insight into the pre-COVID global and Turkish mining industries and investigates the impact of the pandemic on the global and Turkish mining sectors. Furthermore, the study suggests numerous measures that should be adopted in mines to limit the spread of COVID-19 and conduct mining operations safely and efficiently. METHODS: An extensive literature review was conducted and relevant papers on the importance and benefits of the mining industry, the Turkish and global mining industry, and the impact of COVID-19 on the Turkish and global mining industry were studied. RESULTS: The COVID-19 crisis has deeply affected metal and mineral production and the economic sectors that depend on the mining industry for supplies. The most significant impacts caused by the COVID-19 pandemic on the global mining industry consist of the drastic decline in demand and production and the decrease in the prices of several commodities. As with any complex global situation, the mining industries of some countries were affected more than others by the COVID-19 crisis. The Turkish mining industry was to some extent affected by the COVID-19 crisis, but it quickly recovered. CONCLUSIONS: An efficient planning of operations and adopting effective measures and precautions enable limiting the spread of COVID-19 in quarries and mines.
Citation - WoS: 34
Citation - Scopus: 41
Investigation of Micropollutants Removal From Landfill Leachate in a Full-Scale Advanced Treatment Plant in Istanbul City, Turkey
(ELSEVIER, 2020) Argun, Mehmet Emin; Akkuş, Mehmet; Ateş, Havva
Although the levels of micropollutants in landfill leachate and municipal wastewater are well-established, the individual removal mechanisms and the fate of micropollutants throughout a landfill leachate treatment plant (LTP) were seldom investigated. Therefore, the determination of the removal efficiencies and the fates of micropollutants in a full-scale leachate treatment plant located in the largest city of Turkey were aimed in this study. Some important processes, such as equalization pond, bioreactor, ultrafiltration (UF) and nanofiltration (NF), are being operated in the treatment plant. Landfill leachatewas characterized as an intense pollution source of macro and micropollutants compared to other water types. Chemical oxygen demand (COD), NH3, suspended solids (SS) and electrical conductivity (EC) values of the landfill leachate (and their removal efficiencies in the treatment plant) were determined as 18,656 +/- 12,098 mg/L (98%), 3090 +/- 845 mg/L (99%), 4175 +/- 1832 mg/L (95%) and 31 +/- 2 mS/cm (51%), respectively. Within the scope of the study, the most frequently and abundantly detected micropollutants in the treatment plant were found as heavy metals (8 +/- 1.7 mg/L), VOCs (38 +/- 2 mu g/L), alkylphenols (9 +/- 3 mu g/L) and phthalates (8 +/- 3 mu g/L) and the overall removal efficiencies of these micropollutants ranged from -11% to 100% in the treatment processes. The main removal mechanism of VOCs in the aerobic treatment process has been found as the volatilization due to Henry constants greater than 100 Pa.m(3)/mol. However, the molecular weight cut off restriction of UF membrane has caused to less or negative removal efficiencies for some VOCs. The biological treatment unit which consists of sequential anoxic and oxic units (A/O) was found effective on the removal of PAHs (62%) and alkylphenols (87%). It was inferred that both NO3 accumulation in anoxic reactor, high hydraulic retention time (HRT) and sludge retention time (SRT) in aerobic reactor provide higher biodegradation and volatilization efficiencies as compared to the literature. Membrane processes were more effective on the removal of alkylphenols (60-80%) and pesticides (59-74%) in terms of influent and effluent loads of each unit. Removal efficiencies for Cu, Ni and Cr, which were the dominant heavy metals, were determined as 92, 91 and 51%, respectively and the main removal mechanism for heavy metals has thought to be coprecipitation of suspended solids by microbial biopolymers in the bioreactor and the separation of colloids during membrane filtration. Total effluent loads of the LTP for VOCs, semi volatiles and heavymetalswere 1.0 g/day, 5.2 g/day and 1.5 kg/day, respectively. It has been concluded that the LTP was effectively removing both conventional pollutants and micropollutants with the specific operation costs of 0.27 $/(kg of removed COD), 0.13 $/(g of removed VOCs), 0.35 $/(g of removed SVOCs) and 2.6 $/(kg of removed metals). (C) 2020 Elsevier B.V. All rights reserved.
Citation - WoS: 6
Citation - Scopus: 7
Measurement and Evaluation of Particulate Matter and Atmospheric Heavy Metal Pollution in Konya Province, Turkey
(SPRINGER, 2021) Kunt, Fatma; Ayturan, Zeynep Cansu; Yümün, Feray; Karagönen, İlknur; Semerci, Mümin; Akgün, Mehmet
Air pollution has negative effects on human health, visibility, materials, plants, and animal health. Particulate matters are one of the most important air pollutants that may create a risk for human health. Especially particulate matters, which are composed of heavy metals and cancer-causing chemicals such as PAH, dioxin, furan, can cause serious reactions in the respiratory tract. Heavy metals are so important because of their capability of accumulation in human tissues. Almost 0.01-3% of heavy metal content may be found in particulate matter. Coarse particulate matters (PM10) which have smaller diameters than 10 microns may enter from the respiratory system and reach the lungs. In this study, PM10 concentrations and heavy metal content (Lead, Nickel, Arsenic, Cadmium) of the samples were measured and evaluated concerning present regulations and limit values for different points in Konya Province, Turkey. The samples were taken at different seasons such as winter, summer, and spring for 16 days. According to the results of this study, in the winter season, PM10 concentration of the measurement point (Directorate Building) located at the settlement area was found the highest. In the summer season, PM10 concentration of the measurement point (Sille Junction) located at crossroads was found the highest. In spring season, maximum PM10 concentration was detected on the measurement point (KOS base station) located in the industrial area. Moreover, daily average nickel (Ni) concentration measured at KOS base station was found the highest and some other station located close to the industrial area and settlement areas were detected higher than average annual limit values in the winter period. Daily average lead (Pb) value was found at least 67% and maximum 98% higher at Sille and Besyol Junctions, but below the annual average limits. Daily average cadmium (Cd) value was mostly calculated in the Directorate Building winter measurement, but it did not exceed the limit value during the measurement periods. Daily average arsenic (As) values at Directorate Building and Karkent measurement points in the winter period were found higher than the annual average limit values. Only daily average nickel concentrations were detected higher than the annual average limits for the summer and spring period at the KOS base station measurement point.
Citation - WoS: 5
Citation - Scopus: 7
Variations of 222rn Concentrations Over Active Fault System in Simav, Kütahya, Western Turkey: Possible Causes for Soil-Gas 222rn Anomalies
(Elsevier Ltd, 2022) Manisa, Kaan; Erdoğan, Mehmet; Zedef, Veysel; Bircan, Hasan; Biçer, Aahmet
Soil-gas 222Rn concentrations were investigated on an active Simav Graben/Fault System in Western Turkey. Measurements to understand the causes of variations in soil-gas 222Rn were conducted in three distinct sections such that seven selected measurement points in each section lie on a line that is approximately perpendicular to the main fault line. It was found out in each section that values obtained at two adjacent points were abnormally higher than the rest. The corresponding concentrations were measured as 60.76–63.93 kBq/m3, 33.00–45.78 kBq/m3, and 56.20–84.69 kBq/m3 on the first, second, and third lines, respectively. These values, which differ significantly from measurements conducted on a similar line, are thought to be stemming from crustal stress caused by faulting or acidic-intrusive rocks in the region. © 2022 Elsevier Ltd

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