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https://hdl.handle.net/20.500.13091/3218
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DC Field | Value | Language |
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dc.contributor.author | Çetinkaya, Zeynep | - |
dc.contributor.author | Güneş, Eda | - |
dc.contributor.author | Şavklıyıldız, İlyas | - |
dc.date.accessioned | 2022-11-28T16:57:08Z | - |
dc.date.available | 2022-11-28T16:57:08Z | - |
dc.date.issued | 2023 | - |
dc.identifier.issn | 0254-0584 | - |
dc.identifier.uri | https://doi.org/10.1016/j.matchemphys.2022.126900 | - |
dc.identifier.uri | https://doi.org/10.1016/j.matchemphys.2022.126900 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.13091/3218 | - |
dc.description.abstract | ZrO2–SnO2 nanocomposition were produced in nanofibers (NFs) form with three various mixing volume ratio by electrospinning technique. The microstructure and morphological characterization of NFs reveals the ternary system of ZrO2–SnO2–ZrSnO4. Furthermore, Band gap structure of NFs was varied with the composition ratio which consequently affect the Flash sintering (FS) event. The FS experiments were utilized under thermal (844–878 °C) and electric field (420 V/mm) with 3.77 mA/mm2 current cutoff. Highly dense nanocomposition were obtained in less than 80secs with a max power absorption of 1.58 W/mm3. Thanks to low sintering temperature and time, nanostructured surface morphology were acquired which is crucial for biochemical properties of nanocompositions. Drosophila melanogaster food was covered with sintered nanocompositions and the control food. The toxicity of the nanomaterial in the insect, survival rate(%), development time(days) were investigated. In order to support the results, biochemical analyzes (total oxidative level-TOS, total antioxidant level-TAS and oxidative stress index-OSI) were performed in adults. In addition, antimicrobial activity was evaluated with Escherichia coli and Staphylococcus aureus. It was determined that the nanomaterials had an antimicrobial effect along with non-toxic effect on the insect. Besides, it did not change the survival rate of the insect in all groups. Although there was a one-day difference in development times, it did not cause a statistical change in the OSIs of female and male individuals. We believe that the synthesized nanocompositions can be used as a valid candidate in the healthcare system, such as dental implants, due to its antimicrobial effect and non-toxicity in the model organism. © 2022 Elsevier B.V. | en_US |
dc.description.sponsorship | Konya Teknik Üniversitesi, KTÜN: BAP- 221019015; Necmettin Erbakan Üniversitesi | en_US |
dc.description.sponsorship | The authors gratefully acknowledge the financial support provided by the Scientific Research Projects Coordination Unit of Konya Technical University (Contract # BAP- 221019015 ). | en_US |
dc.description.sponsorship | Examination of bandgap properties for homogeneously structured composite ZrO2–SnO2 NFs has been additionally checked for supporting evidence for FS properties research. Fig. 6 shows the absorbance behavior of electrospun ZrO2–SnO2–ZrSnO4 CNFs in the wavelength range of 200–700 nm. As illustrated in Fig. 6, NFs displayed absorbance not only in UV but also in the visible region. Pure and composite ZrO2 NFs were investigated using UV–vis spectrophotometer in the wavelength range between 200 and 700 nm to determine the effect of SnO2 composition amount on the band gap properties of the NFs. The optical absorption of pure and composite ZrSn, Zr2Sn and 2ZrSn CNFs are given in Fig. 6a. For the comparison with the NFs pure SnO2 NF's absorbance value is also included in the graph. As seen Fig. 6a, curves of the pure and NFs display absorption bands in the ultraviolet wavelength area but close to the visible-light range.The authors gratefully acknowledge the financial support provided by the Scientific Research Projects Coordination Unit of Konya Technical University (Contract # BAP- 221019015).The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Zeynep Cetinkaya reports financial support was provided by Konya Technical University. Zeynep Cetinkaya reports a relationship with Konya Technical University that includes: funding grants. Corresponding author and co-author (Zeynep Çetinkaya and İlyas Şavkliyildiz, respectively) employed by Konya Technical University. Eda Güneş employed by Necmettin Erbakan University. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier Ltd | en_US |
dc.relation.ispartof | Materials Chemistry and Physics | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Antimicrobial activity | en_US |
dc.subject | Composite nanofiber | en_US |
dc.subject | Flash sintering | en_US |
dc.subject | Larval toxicity | en_US |
dc.subject | Model organism | en_US |
dc.subject | Electric fields | en_US |
dc.subject | Energy gap | en_US |
dc.subject | Escherichia coli | en_US |
dc.subject | Morphology | en_US |
dc.subject | Sintering | en_US |
dc.subject | Surface morphology | en_US |
dc.subject | Toxicity | en_US |
dc.subject | Zirconia | en_US |
dc.subject | Anti-microbial activity | en_US |
dc.subject | Anti-microbial effects | en_US |
dc.subject | Biochemical properties | en_US |
dc.subject | Composite nanofibers | en_US |
dc.subject | Development time | en_US |
dc.subject | Flash sintering | en_US |
dc.subject | Larval toxicity | en_US |
dc.subject | Model organisms | en_US |
dc.subject | Survival rate | en_US |
dc.subject | Volume ratio | en_US |
dc.subject | Nanofibers | en_US |
dc.title | Investigation of biochemical properties of flash sintered ZrO2–SnO2 nanofibers | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1016/j.matchemphys.2022.126900 | - |
dc.identifier.scopus | 2-s2.0-85140804316 | en_US |
dc.department | Fakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümü | en_US |
dc.identifier.volume | 293 | en_US |
dc.identifier.wos | WOS:000882390100001 | en_US |
dc.institutionauthor | Çetinkaya, Zeynep | - |
dc.institutionauthor | Şavklıyıldız, İlyas | - |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 57212081732 | - |
dc.authorscopusid | 57193812931 | - |
dc.authorscopusid | 53164635500 | - |
dc.identifier.scopusquality | Q1 | - |
item.languageiso639-1 | en | - |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
item.openairetype | Article | - |
item.grantfulltext | embargo_20300101 | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
crisitem.author.dept | 02.11. Department of Metallurgical and Materials Engineering | - |
Appears in Collections: | Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections |
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