Please use this identifier to cite or link to this item: https://hdl.handle.net/20.500.13091/2452
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dc.contributor.authorKara, Duygu Akın-
dc.contributor.authorBurnett, Edmund K.-
dc.contributor.authorKara, Koray-
dc.contributor.authorUsluer, Özlem-
dc.contributor.authorCherniawski, Benjamin P.-
dc.contributor.authorBarron, Edward J.-
dc.contributor.authorBriseno, Alejandro L.-
dc.contributor.authorKuş, Mahmut-
dc.date.accessioned2022-05-23T20:22:45Z-
dc.date.available2022-05-23T20:22:45Z-
dc.date.issued2022-
dc.identifier.issn1463-9076-
dc.identifier.issn1463-9084-
dc.identifier.urihttps://doi.org/10.1039/d2cp00985d-
dc.identifier.urihttps://hdl.handle.net/20.500.13091/2452-
dc.description.abstractSingle crystal studies provide a better understanding of the basic properties of organic photovoltaic devices. Therefore, in this work, rubrene single crystals with a thickness of 250 nm to 1000 nm were used to produce an inverted bilayer organic solar cell. Subsequently, polycrystalline rubrene (orthorhombic, triclinic) and amorphous bilayer solar cells of the same thickness as single crystals were studied to make comparisons across platforms. To investigate how single crystal, polycrystalline (triclinic-orthorhombic) and amorphous forms alter the charge carrier recombination mechanism at the rubrene/PCBM interface, light intensity measurements were carried out. The light intensity dependency of the J(SC), V-OC and FF parameters in organic solar cells with different forms of rubrene was determined. Monomolecular (Shockley Read Hall) recombination is observed in devices employing amorphous and polycrystalline rubrene in addition to bimolecular recombination, whereas the single crystal device is weakly affected by trap assisted SRH recombination due to reduced trap states at the donor acceptor interface. To date, the proposed work is the only systematic study examining transport and interface recombination mechanisms in organic solar cells produced by different structure forms of rubrene.en_US
dc.description.sponsorshipOffice of Naval Research [N0001416-1-2612, N000147-14-1-0053]; Turkey research fellowship [TUBITAK 2214/A-1059B141501315]; Turkey Scholarship Council [2214/A-1059B141501316]; 1003 -Primary Subjects R&D Funding Program [218M940]en_US
dc.description.sponsorshipD. A. K. acknowledges the Turkey research fellowship (TUBITAK 2214/A-1059B141501315). K. K. thanks the Turkey Scholarship Council (2214/A-1059B141501316). B. G acknowledges the 1003 -Primary Subjects R&D Funding Program (218M940) and A. L. B. acknowledges the Office of Naval Research (N0001416-1-2612 and N000147-14-1-0053).en_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofPhysical Chemistry Chemical Physicsen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectOpen-Circuit Voltageen_US
dc.subjectTemperatureen_US
dc.subjectMorphologyen_US
dc.subjectTransporten_US
dc.subjectMobilityen_US
dc.subjectGrowthen_US
dc.subjectOrderen_US
dc.subjectFilmsen_US
dc.titleRubrene single crystal solar cells and the effect of crystallinity on interfacial recombinationen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/d2cp00985d-
dc.identifier.pmid35450982en_US
dc.identifier.scopus2-s2.0-85129693482en_US
dc.departmentFakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Kimya Mühendisliği Bölümüen_US
dc.authoridAKIN KARA, DUYGU/0000-0002-6767-5729-
dc.authoridBarron, Edward/0000-0002-1091-1217-
dc.authorwosidGultekin, Burak/AAC-9472-2022-
dc.identifier.volume24en_US
dc.identifier.issue18en_US
dc.identifier.startpage10869en_US
dc.identifier.endpage10876en_US
dc.identifier.wosWOS:000784790400001en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.scopusqualityQ1-
item.openairetypeArticle-
item.languageiso639-1en-
item.cerifentitytypePublications-
item.grantfulltextembargo_20300101-
item.fulltextWith Fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
crisitem.author.dept02.01. Department of Chemical Engineering-
Appears in Collections:Mühendislik ve Doğa Bilimleri Fakültesi Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collections
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collections
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collections
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