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https://hdl.handle.net/20.500.13091/2028
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Karataş, Özgül | - |
dc.contributor.author | Ceylan, Yusuf | - |
dc.date.accessioned | 2022-02-26T20:54:24Z | - |
dc.date.available | 2022-02-26T20:54:24Z | - |
dc.date.issued | 2020 | - |
dc.identifier.issn | 2667-8055 | - |
dc.identifier.uri | https://doi.org/10.36306/konjes.821866 | - |
dc.identifier.uri | https://dergipark.org.tr/tr/pub/konjes/issue/58996/821866 | - |
dc.identifier.uri | https://dergipark.org.tr/tr/download/article-file/1382223 | - |
dc.identifier.uri | https://hdl.handle.net/20.500.13091/2028 | - |
dc.description | DergiPark: 821866 | en_US |
dc.description | konjes | en_US |
dc.description.abstract | Kaynaşık bir heteroksil bileşiği olan yeni epoxyisoquinoline sulfonamide maddesi (I), (4aS,7S,8aR)-8a-bromo-7-methyl-2-tosyl-2,3,4,7,8,8a-hexahydro-1H-4a,7-epoxyisoquinoline, yeşil ve kademeli bir süreç ile sentezlendi. Daha sonra doz hızı of 0.981 kGy/h olan 60Co-gama (?) kaynağı ile oda sıcaklığında 72 saat ışınlandı. I bileşiğinin EPR spektrumları, 150-340 K sıcaklık aralığında X-bant EPR spektrometresi kullanılarak manyetik alanda üç farklı yönelimde kaydedildi. Elde edilen sonuçlara göre, örneğe ait izotropik spektrumların olduğu görüldü ve C ?H_3 H radikalinin varlığı gözlemlendi. Sonuçlar, Bruker WinEPR-Simfonia programı kullanılarak fit edildi. Radikalin aşırı ince yapı sabiti (A) ile deneysel izotropik spektroskopik değeri (g) hesaplandı. | en_US |
dc.description.abstract | A new epoxyisoquinoline sulfonamide as a fused heterocycle compound (I), (4aS,7S,8aR)-8a-bromo-7-methyl-2-tosyl-2,3,4,7,8,8a-hexahydro-1H-4a,7-epoxyisoquinoline was synthesized using green and cascade progress which was then irradiated by 60Co-gamma (?) ray source with a dose speed of 0.981 kGy/h at the room temperature for 72h. EPR spectra of I compound were measured at different orientations in magnetic field with X-band EPR spectrometer along the temperatures between 150-340 K. Isotropic spectrum was obtained without depending on temperature and radical structure, C ?H_3 H was observed. Radical was simulated using the Bruker software WinEPR-Simfonia and the experimental isotropic g-value with hyperfine coupling constant of radical was calculated. | en_US |
dc.language.iso | tr | en_US |
dc.publisher | Konya Technical University | en_US |
dc.relation.ispartof | Konya Mühendislik Bilimleri Dergisi | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | EPR | en_US |
dc.subject | Işınlama Etkileri | en_US |
dc.subject | Radikal | en_US |
dc.subject | Sentez | en_US |
dc.subject | Sulfonamide | en_US |
dc.subject | EPR | en_US |
dc.subject | Irradiation effects | en_US |
dc.subject | Radical | en_US |
dc.subject | Synthesis | en_US |
dc.subject | Sulfonamide | en_US |
dc.title | Gama Işınları ile Işınlanmış Yeni Bir Isoquinoline Sulfonamide (C17H20BrNO3S) Maddesinin X-Bant EPR Çalışması | en_US |
dc.title.alternative | X-BAND EPR STUDIES OF GAMMA IRRADIATED A NEW ISOQUINOLINE SULFONAMIDE: C17H20BrNO3S | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.36306/konjes.821866 | - |
dc.department | Meslek Yüksekokulları, Teknik Bilimler Meslek Yüksekokulu, Elektrik ve Enerji Bölümü | en_US |
dc.identifier.volume | 8 | en_US |
dc.identifier.startpage | 46 | en_US |
dc.identifier.endpage | 52 | en_US |
dc.relation.publicationcategory | Makale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.trdizinid | 491269 | en_US |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.languageiso639-1 | tr | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.openairetype | Article | - |
item.fulltext | With Fulltext | - |
crisitem.author.dept | 07. 10. Department of Electricity and Energy | - |
Appears in Collections: | Konya Mühendislik Bilimleri Dergisi Teknik Bilimler Meslek Yüksekokulu Koleskiyonu TR Dizin İndeksli Yayınlar Koleksiyonu / TR Dizin Indexed Publications Collections |
Files in This Item:
File | Size | Format | |
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10.36306-konjes.821866-1382223.pdf | 645.93 kB | Adobe PDF | View/Open |
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